Wembley is to host seven games during the 2020 European Championships after Brussels was ruled out.
The Belgian capital lost the right to host matches as a new stadium is still being built and UEFA was unable to secure the necessary guarantees.
Wembley was already scheduled to hold the semi-finals and final but will now also host three group games and a last 16 tie.
The 2020 tournament, which runs from 12 June until 12 July that year, is the first European Championship to be played under a new format with group games spread across several countries, with the opening match to be played at the Stadio Olimpico in Rome.